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Ice core concentration and stable isotope measurements of atmospheric CH 4 give valuable insights into the CH 4 cycle of the past. New carbon and hydrogen stable isotope CH 4 data measured on ice from both Greenland and Antarctica over the Holocene allow us to draw conclusions on the methane emission processes. In particular, our results cast doubt on a hypothesis proposing early human land use to be responsible for the atmospheric methane concentration increase in the second half of the Holocene. To quantify the impact of El Nino–Southern Oscillation (ENSO) climate events on the methane budget, we studied the correlation between CH 4 time series and ENSO indices. We find that ENSO explains less than one-third of the variability in CH 4 levels and their stable carbon isotopes, which constrain the source processes of emissions. ENSO forcing of the CH 4 cycle is too small, episodic, and regional to force atmospheric trends, which are more likely caused by agricultural or industrial emissions. Nitrous oxide (N 2O) is an important and strong greenhouse gas in the atmosphere and part of climate.

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N 2O is produced by microbes in terrestrial and aquatic ecosystems. The properties of each specific molecule can be used to determine the source. We implemented continuous measurements of N 2O during incubation of denitrifying bacteria and believe that similar experiments will lead to a better understanding of N 2O turnover and on the biotic mechanisms behind greenhouse gas exchange of the globe. The quantitative importance of northern lakes in terrestrial carbon budgets is uncertain, as year-round observations of carbon fluxes are rare. We measured CH 4 and CO 2 fluxes from a subarctic lake and nearby fen during 2.5 years with one eddy covariance system.

We identified drivers of seasonal variability in lake fluxes and show the importance of winter and spring for annual carbon exchange in both ecosystems. The lake as a source of atmospheric carbon partially compensates the fen carbon sink. This study quantified, for the first time, simultaneous rates of carbon dioxide (CO 2) and nitrous oxide (N 2O) from a Mediterranean riparian forest. Our results showed a strong linkage between riparian hydrology, soil microbial processes, and greenhouse gas (GHG) emissions. High CO 2 effluxes occurred all year long, while N 2O emissions were generally low and confined to saturated soils. Overall, this study shows that riparian soils can be hotspots of GHG emissions within Mediterranean catchment.